Other Kinds of Water-Reducing Agents
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Russia and Ukraine is an important exporters of oil, natural gas, metals, fertilizers, rare gases and other industrial raw materials. Affected by the further intensification of the tension of the war, the global market has become more worried about the supply of the water reducer, and panic spreads in the futures market. Prices of commodities such as aluminum and nickel are at recent highs on concerns that supplies will fall. Russia accounts for 49 percent of global exports of nickel, 42 percent of palladium, 26 percent of aluminum and 13 percent of platinum, and is a significant exporter of steel and copper. Palladium is an important metal for sensors and memory. In addition, Russia is the world's largest exporter of nitrogen fertilizer, the second largest exporter of potash fertilizer, and the third-largest exporter of phosphate fertilizer. Ukraine is also an important producer of nitrogen fertilizer. Russia's natural gas supply also has a significant impact on the global fertilizer industry and water reducer industry, especially in Europe. The price of the water reducer will also fluctuate to some extent. Russia carries out crude gas separation, and Ukraine is responsible for refined exports. Ukraine supplies 70% of the world's neon, 40% of krypton and 30% of xenon. These three gases are the materials used to make chips.
Water reducing agents can be divided into ordinary water-reducing agents (also known as the plasticizing agent, whose water reducing rate is not less than 8%, represented by lignin sulfonic acid salts), high-efficient water-reducing agents (also called superplasticizer, whose water reducing rate is not less than 14%, including naphthalene, melamine, amino sulfonic acid salt, aliphatic, etc.) and high-performance water reducing agent (the water reducing rate is not less than 25%, represented by the polycarboxylate water-reducing agent).
Following is an introduction to five kinds of water-reducing agents.
Sulfamate High-efficient Water Reducing Agent:
The chemical name is aromatic amino sulfonate polymer. The production process is to use sodium aminobenzene sulfonic acid, and phenol as raw material, through addition, and the polycondensation reaction, a kind of polymerization of oita polymers will be produced. The water-reducing rate can reach 30%. The cost is relatively high, and it is easy to bleed. When used in combination with the naphthalene series high efficient water reducing agent, it can solve the problem of the naphthalene series high efficient water reducing agent and compatibility of cement.
Sulfamate superplasticizer is a kind of monocyclic aromatic hydrocarbon type superplasticizer, mainly composed of p-sulfamate and monocyclic aromatic hydrocarbon derivatives. Phenol compounds will be combined with formaldehyde under acidic or alkaline conditions heat condensation.
The molecular structure of sulfamic acid superplasticizer is complex, and different monomers will have different molecular structures.
The synthesis process is through the sulfamate superplasticizer and polyoxyeolefin compound polycondensation or with other compounds, such as lignosulfonate, catalytic graft to modify the sulfamate superplasticizer. The sulfamate series water reducing agent modified by polyoxy olefins polycondensation combines the advantages of polycarboxylate series and sulfamate series water reducing agent and has good working performance and early strength, but the raw material price is expensive and the production cost is high.
The graft copolymerization of lignosulfonate and sulfamic acid superplasticizer can reduce the production cost and improve the segregation and bleeding of sulfamic acid superplasticizer.
Fatty Acids High-efficient Water-reducing Agents:
The chemical name is aliphatic hydroxyl sulfonate polymer. The raw materials are mainly acetone, formaldehyde, Na2SO3, Na2S2O5, catalyst, etc. It is brownish-red liquid. The water reduction rate can reach 20%, and it can be used for low-grade concrete and will make concrete stain.
HSB aliphatic superplasticizer
HSB (High Strence Bing) is a carbonyl pyroaldehyde synthesized by sulfonation of polymer. Hydrophobic main chain for aliphatic hydrocarbons, it does not pollute the environment and does not damage human health. It has wide applicability to cement, obvious concrete enhancement effect, and small slump loss. Under conditions of low temperature, there is no sodium sulfate crystallization phenomenon. It is widely used in the preparation of pumping agents, delay setting, early strength, antifreeze, air, and other kinds of individual water reducing agents, and can also be used with naphthalene series water reducing agent, amino water reducing agent, polycarboxylate water reducing agent compound.
1. High water reduction rate. Dosage is 1-2%, the water reduction rate is up to 15-25%. Under the condition of the same strength slump, adding HSB can save cement consumption by 25-30%.
2. Early strength and obvious enhancement effect. Concrete mixed with HSB can reach 60-70% of the design strength in three days, 100% in seven days, and 30-40% higher than blank concrete strength in 28 days.
3. High plastic. Concrete slump loss is small, with almost no loss for 60 min and 10-20% for 90 min;
4. Wide applicability to cement, workability, and good cohesion. Good compatibility with other kinds of admixtures;
5. It can significantly improve the freeze-thaw resistance, seepage resistance, sulfate resistance of concrete, and comprehensively improve the other physical properties of concrete;
6. It is especially suitable for the following concrete: flow plasticized concrete, natural curing, steam curing concrete, impermeable waterproof concrete, durable freeze-thaw resistant concrete, sulfate resistant Marine engineering concrete, and reinforced concrete, prestressed concrete;
7. HSB is non-toxic, non-flammable, non-corrosive to steel bars, and has no sodium sulfate crystals in winter.
It is a new type of high-performance water reducing agent, which has an excellent water reduction rate, fluidity, and permeability. Obviously, it can enhance the strength of cement mortar, but the production process is complex, and the general price is higher.
It is a biopolymer made from milk precipitated with acid and dried in a cylinder.
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The development of the Russia-Ukraine conflict will continue to dominate the commodity prices such as the water reducer in the future. If the conflict eases or cools, Russia and Ukraine go back to negotiate, commodity prices would fall. However, if the situation between Russia and Ukraine deteriorates further, or evolves into a full-scale war, the price of the water reducer is predicted to see further improvement over the coming days.