Influence of concrete raw materials on the properties of polycarboxylate superplasticizer

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Russian president demanded that exports of Russian gas to "unfriendly" countries be settled in rubles. The demand has raised concerns in Germany about possible supply disruptions and the impact on industry and households if utilities do not pay in robles. Europe gets about 40% of its gas from Russia. Last year, Europe imported about 155 billion cubic meters. Germany, Europe's largest economy, depends heavily on Russian gas.

The chief executive of Germany's E.ON said the German economy would face "significant damage, which should be avoided if possible" without Russian supplies. He also said it would take Germany three years to wean itself off Russian gas.  

In the event of a supply disruption, Germany's gas network regulator would prioritize home heating over industrial use, so energy-hungry manufacturers such as steelmakers would be the first to suffer, he said.

The volatile international situations will continue to affect the markets and prices of many commodities like the polycarboxylate superplasticizer.

Concrete is an indispensable raw material in the construction of construction projects. In the process of preparing concrete, in order to improve the performance of concrete, it is necessary to add water reducing agent after adding water, stone, sand and cement. Then sufficient mixing can greatly improve the fluidity and strength of concrete. The more common superplasticizers in daily work are mainly polycarboxylate superplasticizers. This water reducing agent is widely used due to its advantages of high water reduction rate, high slump retention performance, and good economy.

1 Analysis of the mechanism of action of polycarboxylate superplasticizers

Polycarboxylate superplasticizer is mainly composed of carboxylic acid grafted polymer, light brown, is a transparent liquid. Its main mechanism of action includes two kinds of maintaining dispersion mechanism and dispersion mechanism. Polycarboxylate superplasticizers are currently widely used in the field of construction engineering because polycarboxylate superplasticizers have very stable chemical properties compared to ordinary superplasticizers; they are transparent liquids and are easy to transport. In this way, a lot of transportation costs are saved, and the waste of resources is also reduced.

At present, the most used polycarboxylate water reducer is mainly acrylic acid as the main chain, but it is the hydroxyl and carboxyl molecules that play a role. These two molecules can combine with water molecules in concrete, thereby promoting The flocculation structure is destroyed, so that the microstructure of the concrete changes, which makes the concrete set and harden faster. The relevant chemical molecules in the polycarboxylate water reducer will be combined with the cement particles, which will speed up the fluidity of the concrete, and then obtain the desired ideal state, which can further highlight the characteristics of the concrete. However, in the process of actually using polycarboxylate water reducer, this water reducer has higher requirements on the outside temperature range during the use of concrete. Whether the construction temperature is too high or too low, it will affect the characteristics of the polycarboxylate water reducer, so that the ideal effect cannot be achieved.

2 Water reduction rates of different dosages

In this paper, ten kinds of water reducing agents (PCE-1~PCE-10) are selected for analysis, and the specific water reducing rate is shown in Figure 1.

When the content of polycarboxylate superplasticizer is 0.15%, the water reduction rates of PCE-1, PCE-2, PCE-4, PCE-6 and PCE-7 are all higher than 20%, showing a higher Water reducing rate; once the content of polycarboxylate water reducing agent is higher, that is, when it reaches 0.2%, these water reducing rates will be higher (25%-30%); When the dosage is not higher than 0.3% and not lower than 0.25%, the water reduction rates of PCE-2, PCE-4, PCE-6, PCE-7 and PCE8 all reach (30%) ~35%).

3 Analysis of the influence of concrete raw materials on polycarboxylate water reducer

3.1 Influence of cement on polycarboxylate superplasticizer

There are essential differences between ordinary lignosulfonate-based superplasticizers, naphthalene-based superplasticizers and polycarboxylic acid-based superplasticizers. Polycarboxylate superplasticizers have the advantages of being environmentally friendly, harmless, strong in slump retention and high in water reduction rate, so they are widely used. However, this water reducing agent also has certain defects, that is, the problem of poor adaptability, but this is also a common defect of ordinary water reducing agents. For example, when a certain cement is applied, there may be characteristics such as poor fluidity of the cement slurry and poor water reduction effect, and the main reason for this phenomenon is due to the molecular structure of the substance itself. composition and surface properties.

3.2 Influence of fine aggregate on polycarboxylate superplasticizer

Machine-made sand and natural sand are the more commonly used fine aggregates in concrete, and are one of the raw materials for concrete preparation. Natural sand is divided into three types: river sand, mountain sand and sea sand. However, it should be noted that in the process of preparing concrete, do not use a large amount of polycarboxylate water-reducing agent. Once excessive, it will inevitably react with fine aggregates, which will not only affect the slump of concrete, but also affect the concrete. strength is adversely affected. In addition, another important factor that affects the adaptability of concrete and polycarboxylate superplasticizers is the content of stone powder in the sand. If sand with high stone powder content is used in the process of preparing concrete, it is very likely to have a series of effects on the fluidity of concrete. In addition, other characteristics of fine aggregates will also affect the adaptability of concrete and polycarboxylate superplasticizers, such as the thickness of sand. Generally speaking, if the fineness of the sand is less than the standard value, it will cause rapid loss of fluidity of the concrete. At the same time, the sand ratio and the residual sulfate and chloride ions in the sea sand will reduce the water of the polycarboxylate system. The adaptability of the agent has a certain degree of influence. In addition to the above factors, the content of mud in the sand will also affect the adaptability and performance of the polycarboxylate superplasticizer. The main reason is that the soil has a strong adsorption force, and this strong adsorption force will affect the water reducing rate of the water reducing agent. The mud content of different substances will also be different. Generally speaking, the content of soil in the sandstone will have a greater effect on the polycarboxylate superplasticizer. When the mud content in the sandstone exceeds 3%, the performance of the water reducer will be significantly reduced. , even adding an appropriate amount of mixing will not promote the fluidity of concrete.

3.3 Influence of coarse aggregate on polycarboxylate superplasticizer

Another important factor affecting polycarboxylate superplasticizer is coarse aggregate. This performance is mainly reflected in the gradation of the stone and the content of needle flakes. Even for stones with the same gradation, if the acicular content of the stones increases, the flow rate of the concrete will inevitably slow down, and the decrease in expansion may lead to bleeding or segregation. In addition, the water absorption of coarse aggregates with different thicknesses will also be different. Generally speaking, the water absorption of fine aggregate is higher than that of coarse aggregate. Even changing the air content or dosage of the water reducing agent cannot achieve the expected purpose. Only by adjusting the mix ratio of concrete can it be changed. Therefore, in the actual construction process, it is necessary to continuously adjust the stone gradation and the mud content of the sand according to the actual situation of the raw materials, and seek the best solution.

4 Conclusion

In summary, admixtures play a vital role in the preparation of high-performance concrete, and are therefore indispensable raw materials in the preparation of concrete. At present, polycarboxylate superplasticizers are widely used due to their many advantages. In order to better promote the further development of this superplasticizer, the mechanism and influence of concrete raw materials on polycarboxylate superplasticizers must be investigated. Carry out in-depth research, and at the same time focus on mastering its laws, so that high-performance polycarboxylate water reducers can be prepared in the later stage.

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Greece will hand over Iranian oil it intercepted from a Russian-flagged tanker to the United States at the request of the U.S. Justice Department, Greek port police said recently, AFP reported. The decision angered Tehran.  

In April, Greek authorities reportedly seized a Russian oil tanker, the Pegas, which was said to be heading to the Turkish port of Marmara.  

Reports say the ship was docked in Calistos Bay with a crew of several people said to be Russian. The Greek coast guard said the ship had been renamed the Lana.  

The report notes that the European Union imposed sanctions on Russia after the conflict broke out in February. Greek authorities seized the tanker in accordance with European Union sanctions.  

According to information at the time, the tanker was carrying 115,000 tons of Iranian oil.  

Iran's Ports and Maritime Organization strongly protested Greece's decision, calling it an "international bandit." "The Islamic Republic of Iran will not give up its legitimate rights and expects the Greek government to abide by its international obligations in the area of navigation and shipping," it said in a statement on its website.  

Iran's Foreign Ministry, through the International Maritime Organization, called on the Greek government to release the tanker and its crew overnight, adding that "the Americans discharged their cargo," the report said.  

Athens did not immediately respond to the Iranian protest and gave no further details about the oil on board or how it was handed over to the United States, the report said.

The polycarboxylate superplasticizer price is expected to increase in the next few days affected by the change in supply and demand markets.

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